Laboratory of Industrial Catalysis (LIC)

Staff   Activity   Granted by   School   Ph.D. Thesis   Works

The laboratory was based in January 1989 by order of the academician Ya.M.Kolotyrkin, the director of the institute at that time. Initial tasks of the laboratory included the expertise of industrial catalytic processes in the plants managed by the Ministry of Chemical Industry of the USSR and the performing investigations aimed to improvement and economization of operating plants.

Head of laboratory: Makhlin Vladiln Abamovich, graduated from Moscow Institute of Fine Chemical Technology by M.V.Lomonosov (MSAFCh), Ph.D. (Engineering Sciences), senior researcher, assistant professor at the sub-faculty of the petrochemical synthesis and synthetic liquid fuel of MSAFCh; author of 78 publications, more than 100 scientific and engineering reports and operating regulations, 11 inventors certificates and patents; editor of several issues of Proceedings of the International School «Chemical Engineering for Advance Technologies», 1994-2002.
The order "Red Banner of Labour" (1978) and the medal "Honoured Inventor" for the development and industrial introduction of new technologies.
Scientific interests: technology of petrochemical synthesis and synthesis of synthetic liquid fuels, kinetics and catalysis, heat and mass transfer in multiphase processes, mathematical modelling and implementation of catalytic processes and reactors, neutralization of technological waste and environmental protection.

Phone/Fax: (007)(495) 917-20-32
E-mail: makhlin(!)cc.nifhi.ac.ru

Staff:

Kolchin Alexey Mikhailovich, senior researcher, graduated from Moscow State University by M.V.Lomonosov, Ph.D. (Chemistry); author more than 50 scientific publications and scientific and engineering reports.
Scientific interests: experimental and theoretical methods of the investigations of kinetics and mechanism of heterogeneous catalytic reactions.

Phone/Fax: (007)(495) 917-20-32
E-mail: kolchin(!)cc.nifhi.ac.ru

Nikitin Vasily Olegovich, researcher, graduated from Moscow State University by M.V.Lomonosov.
Scientific interests: information technologies, mathematical support of scientific investigations using up-to-date instrumental matching.

Phone/Fax: (007)(495) 917-20-32
E-mail: unvasily(!)gagarinclub.ru

Smolyansky Alexander Sergeevich, leading researcher, member of the laboratory since 2005, graduated from Moscow Chemico-Technological Institute by D.I. Mendeleev, Ph.D. (Chemistry); author more than 70 scientific publications and 10 scientific and engineering reports; winner of K.E.Tsiolkovsky Prize.
Scientific interests: application of information technologies in testing new materials, mechanism of primary radiochemical processes in solids.

Phone/Fax: (08439) 747-47
E-mail: assa(!)future.org.ru

Evenchik Alexander Samuilovich, senior researcher, graduated from Moscow Institute of Chemical Engineering, Ph.D. (Engineering Sciences), author of 18 publications, 20 scientific and engineering reports, 2 inventors certificates and patents.
Scientific interests: Mathematical modeling and implementation of catalytic processes and reactors, neutralization of technological waste and environmental protection.

Phone/Fax: (007)(495) 917-20-32
E-mail: evenchik(!)inbox.ru

 Activity of the laboratory:

Analysis of industrial processes
Analysis has been performed and ways for improvement and economization of certain industrial processes have been proposed including such process as:

Process and equipment design:
  • production of methyl chloride from methanol and hydrogen chloride in a catalyst fluidized bed,
  • production of dimethyl ether and high-octane gasoline from synthesis gas (together with the Topchiev Institute Petrochemical Syntesis RAS, Zelinsky Institute of Organic Chemistry RAS and Primors Scientific and Technical Center Rocket-Space Corporation «Energy»,),
  • production of ethylene by oxidative dimerization of metnane (together with by Gubkin State Academy of Oil and Gas),
  • adsorptive purification of waste gases in recuperative sorbents,
  • deep dehydration of solvents,
  • catalytic purifications of waste gases,
  • technology of environmentally safe recovery of detoxication products of organophosphorus poison-gases (together with Topchiev Institute of Petrochemical Synthesis RAS) and organochloric supertoxicants (together with Lomonosiv Moscow State University and GosNIIOChT).
Theoretical and experimental study of:
  • parametric sensitivity of exothermic catalytic processes carrying out in a tubular reactor,
  • dynamics of catalytic processes of waste gases purification in adiabatic reactors,
  • dynamics of cyclic adsorption processes of recuperative waste gases purification.
  • kinetics and mechanism of the reaction of methanol with hydrogen chloride on the reactive aluminium oxide,
  • kinetics and mechanism of methanol dehydration on the reactive aluminium oxide,
  • kinetics and mechanism of aluminium oxide deactivation in the reaction of methanol hydrochlorination,
  • mass transfer in the fluidized bed of a discrete material using local response technique in computer-assisted aerodynamic unit.
The investigations have been granted by:
  • The Soros International Scientific Foundation, grant ¹ RAM300 of 20.03.95 for the project: «Non-stationary processes in reaction and adsorptive conjugative systems».
  • International Science and Technology Center (ISTC), grant ¹ 2995 of 01.05.2005 for the project: «Catalytic technologies based on ensembles of interacting nanoclusters» (together with Lomonosiv Moscow State University, Ioffe Physical Technical Institute, and GosNIIOChT).
Continuing International School "Chemical Engineering Science for Advanced Technologies"
(with the participation of Kurnakov Institute of General and Inorganic Chemistry RAS and Lomonosov State Academy Fine Chemical Technology).
  • The School was organized at Karpov Institute of Physical Chemistry in 1994 ã. Seven sessions took place by now, and collected papers, in total 2739 pages, have been published.
Ph.D. Thesis:
  • Ivanov S.I. «Catalytic interaction of methanol with hydrogen chloride on γ-Al2O3»,
  • Okunev B.N. «Dynamics of adiabatic catalytic reactors of waste gases purification»,
  • Romanchuk S.V. «Mathematical modelling of industrial process of vinyl acetate synthesis in a fluidized bed reactor»,
  • Evenchik A.S. «Modelling and analysis of the process for the production of ethylene oxide by ethylene oxidation with oxygen in a cooled tubular reactor».
The works of laboratory is represented:
  • as publications in scientific journals such as Kinetics and Catalysis, Theoreticheskie Osnovy Khimicheskoi Technologii (Theoretical Foundations of Chemical Technoligy), Khimicheskaya Promyshlennost (Chemical Industry), Chem. Eng. Comm.
  • as reports at Russian and International scientific conferences;
  • as 8 inventors certificates and patents for invention.
Some publications:
  1. Evenchik A.S., Makhlin V.A. Variation of catalyst activity along the catalyst layer in the process for ethylene oxide production under gas-phase promotion. // Kinetics and catalysis. 1989, vol. 30, p. 830-834.
  2. Volin Yu.M., Mascheva L.A., Makhlin V.A., Ostrovsky G.M. The account of flow rate changes in modeling chemical reactor with fixed bed of catalyst. // Theor. Osnovy Khim. Technol. 1989, vol. 23, ¹ 6, p. 777-784.
  3. Zolotarsky V.A., Makhlin V.A. Efficiency of carrying out the reactions of partial and hybrid oxidation under non-stationary conditions with the use of reactor/generator system. // Theor. Osnovy Khim. Technol., 1989, vol. 23, ¹2, p. 202-208.
  4. Evenchik A.S., Makhlin V.A. Parametric sensitivity of catalytic tubular reactor. // Theor. Osnovy Khim. Technol. 1991, vol. 25, ¹ 6, p. 828-835.
  5. Zolotarsky V.A., Makhlin V.A. Mathematical modelling of gasoil cracking of íà silica-alumina ceolite catalyst in a raised bed reactor. Modification of catalyst with olefine. // Kinetics and catalysis. 1991, vol. 32, âûï 1, p. 178-184.
  6. Romanchuk S.V., Kozlova G.A., Serdyuk A.V., Akimov A.M., Motin N.V., Popkov Yu.M., Kryukova G.N., Tarasova D.V., Makhlin V.A. Synthesis of vinyl acetate based on acetylene and acetic acid. Deactivation of catalyst in the reactord with fluidized bed. // Kinetics and Catalysis, vol. 23, ¹ 3, 1992, p.691-696.
  7. Romanchuk S.V., Makhlin V.A., Serdyuk A.V., Akimov A.M. Activity and stability of industrial zinc acetate catalyst of the vinyl acetate synthesis from acetylene and acetic acid. // Ecotechnology and resource saving// Khim. Technol. 1992, ¹5, p.13-18.
  8. Evenchik A.S., Makhlin V.A. Modelling and analysis of the process of ethylene oxide production by oxidation of ethylene-oxygen mixture in a cooking tubular reactor. // Theor. Osnovy Khim. Technol. 1992, vol. 26, ¹ 2, p. 212-227.
  9. Makhlin V.A., Evenchik A.S., Romanchuk S.V., Ivanov S.I., Kolesnikov S.E. « Method for production of methyl chloride». // RF Patent ¹ 2051885, 1992.
  10. Romanchuk S.V., Zolotarsky V.A., Evenchik A.S., Makhlin V.A. The effect of low-capacity internals on the intensity of mass transfer in fluidized bed of discrete material. // Theor. Osnovy Khim. Technol. 1993, vol. 27, ¹ 3, p. 296-300.
  11. Evenchik A.S., Makhlin V.A. Optimal structure of catalyst for the reaction of partial oxidation in a tubular reactor. // Theor. Osnovy Khim. Technol. 1993, vol. 27, ¹ 4, p. 398-402.
  12. Okunev B.N., Zolotarsky V.A., Makhlin V.A. Outer diffusion regime of the catalytic process of waste gases purification in adiabatic reactor // Theor. Osnovy Khim. Technol. 1994, vol.28, ¹ 4, p. 388-399.
  13. Okunev B.N., Makhlin V.A., Romanchuk S.V., Ivanov S.I. Adsorption purification of waste gases for chemico-engineering flowsheets with recycle. // Theor. Osnovy Khim. Technol. 1994, vol. 28, p. 621-626.
  14. Makhlin V.A., Ivanov S.I., Okunev B.N., Romanchuk S.V., Evenchik A.S. A method of adsorption-condensation purification of waste gases. // RF Patent ¹2061530, 1994.
  15. Davydov L.S., Makhlin V.A., Romanchuk S.V. Mathematical modelling and analysis of processes in membrane bioreactors. // Theor. Osnovy Khim. Technol. 1995, vol. 29, ¹ 2, p. 187-191.
  16. Romanchuk S.V., Makhlin V.A. Kinetics of catalyst aging in vinylacetate synthesis in fluidized-bed reactor. Optimum content and zinc acetate distribution in the void structure of catalyst support // Kinetics and catalysis. 1995, vol. 36, ¹ 2, p. 303-310.
  17. Ivanov S.I., Makhlin V.A. Catalytic interaction of methanol with hydrogen chloride on γ-Al2O3. Kinetics and mechanism of reaction. // Kinetics and catalysis. 1996, vol. 37, ¹6, p. 873-879.
  18. Makhlin V.A., Romanchuk S.V.Analysis of the process in industrial fluidized-bed reactor under catalyst aging.// Theor. Osnovy Khim. Technol. 1996, vol. 30, ¹ 1, p. 69-78.
  19. Makhlin V.A., Ivanov S.I. Kinetics of deactivation of oxide aluminium γ in methanol hydrochlorination. // Kinetics and catalysis. 1997, vol. 38, ¹ 6, p. 938-942.
  20. Lin G.I., Rozovsii A.Ya., Grafova G.M., Makhlin V.A., Polikov I.V. Dimethyl syntesis from syngas, in Heterogeneous Catalysis, eds. L. Petrov, Ch. Bonev, G. Kadinov. Proceedings of 9-th International Symposium. Varna. Bulgaria. 2000. pp. 883-888.
  21. Rozovsky A.Ya., Lin G.I., Kubikov V.B., Maidurov N.P., Petrov V.N., Brandt B.B., Makhlin V.A. A combined method for production of dimethyl ether from carbureted hydrogen gases. // RF Patent ¹ 2220939, 2002.
  22. Plachenov B.T., Andryushkin S.M., Petrov S.K., Koveshnikov A.V., Mortikov E.S., Filimonov V.N., Pinchuk V.A., Makhlin V.A., Nikotin O.P., Shevchuk V.T., Krasnik V.V., Nekrasov A.V., Barunin A.A., Kekhva T.E., Lebedev V.N. A method for production of engine fuels// RF Patent ¹ 2226524, 2002.
  23. Plate N.A., Kolbanovsky Yu.A., Bilera I.V., Rossikhin I.V., Makhlin V.A., Torubarov A.I., Petrov S.K. Destruction of reaction masses of detoxication of organophosphorus poison-gases in a two-chamber chemical reactor on the base of rocket technologies. // Proceedings of the First Scientific-practical Conference: «Scientific and technical aspects of security providing during detoxication, storage, and transportation of chemical weapon». Scientific and Technical Center “Federal Agency for Safety Storage and Detoxication of Chemical Weapons, Moscow, 2003, p. 169-180.
  24. Kolbanovsky Yu.A., Makhlin V.A., Bilera I.V., Rossikhin I.V. Technological complex for ecologically safe utilization of reaction masses of detoxication of organophosphorus poison-gases. // Abstract of the Second Scientific-practical Conference: «Scientific and technical aspects of security providing during elimination, storage, and transportation of chemical weapon. “Federal Agency for Safety Storage and Detoxication of Chemical Weapons, Moscow, 2004, p. 54-56.
  25. Rozovskii A.Ya., Slivinskii E. V., Lin G. I., Makhlin V.A., Kolbanovsky Yu.A., Plate N.A. Ecologically benign motor fuels and petrochemicals from alternative raw materials.// Pure and Applied Chemistry, 2004, vol. 76, pp. 1735-1747
  26. Kolbanovsky Yu.A., Makhlin V.A., Bilera I.V., Rossikhin I.V. Technological complex for ecologically safe utilization of reaction masses of detoxication of organophosphorus poison-gases. // Khim. Promyshlennost’ Segodnya, ¹ 7, p.37-44, 2005.
  27. Makhlin V.A. Sooting and soot cleaning – Problems of technology of synthesis gas production by partial oxidation of methane// Khim. Promyshlennost’ Segodnya, ¹8, p. 13-19, 2006.
  28. Makhlin V.A., Dedov A.G., Loktev A.S., Parkhomenko K.V., Telpukhovskaay N.O., Evenchik A.S., Moiseev I.I. Heat and mass transfer in oxidative coupling of methane over a La – Ce oxides catalyst. // Khem. Tekhnologiay, ¹7, p.29-34, 2006.
  29. Makhlin V.A. Heterogeneous Catalytically Processes and Reactors in Industry. // Nauka Proizvodstvu. 2007, ¹1, p. 35-47.
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